Publications: Dr. Shubhankar Kumar Bose

List of Publications

1. Prakash, A; Basappa, S.; Jeebula, B.; Nagaraju, D. H.; Dhayal, R. S.; Bose, S. K.* A Simple Nickel Metal−Organic Framework-Catalyzed Borylation of Aryl Chlorides and Bromides. Org. Lett. 2024, 26, 2569–2573 (I.F. = 5.2).
2. Basappa, S.; Prakash, A; Talekar, S. S.; Mane, M. V.; Bose, S. K.* Facile Synthesis of Vinyl Boronate Esters via Dehydrogenative Borylation of Alkenes Enabled by Co-MOF Catalyst: An Additive Free Approach. ACS Cat., 2024. 14, 3065–3073 (I.F. = 12.9).
3. Saini, S.; Gupta, D. K.; Bhawar, R.; Siddiqui, S.; Mane, M. V.; Bose, S. K. Transition-metal- and solvent-free regioselective hydrosilylation of alkenes and allenes enabled by catalytic sodium tert-butoxide. Green Chem., 2023, 25, 10072-10081 (I. F. = 9.8).
4. Bhawar, R.; Saini, S.; Patil, K. S.; Nagaraju, D. H.; Bose, S. K. Synthesis of and Aryl Boronate Esters via CeO2-Catalyzed Borylation of Alkyl and Aryl Electrophiles Including Alkyl Chlorides. J. Org. Chem. 2023, 88, 16270−16279 (I. F. = 3.6).
5. Basappa, S.; Karupnaswamy, R.; Bose, S. K. Transforming carbon dioxide and carbon monoxide into value-added products: boracarboxylation and boracarbonylation. Catal. Sci. Technol. 2023, 13, DOI: 10.1039/d3cy01181j (I. F. = 5.0)
6. Kumara, K. S. M.; Shivakumar, P.; Ganesh, V.; Budagumpi, S.; Bose, S. K.; Hareesh, K.; Nagaraju, D. H. Hydrogels of PANI Doped with Fe3O4 and GO for Highly Stable Sensor for Sensitive and Selective Determination of Heavy Metal Ions. Inorg. Chem. Commun. 2023, 158, 111553. (I. F. = 3.8)
7. Saini, S.; Bhawar, R.; Srivastava, A. K.; M, S.; Garg, K.; Bose, S. K.* Transition Metal- and Solvent-Free Anti-Markovnikov Selective Protoboration of Alkenes with Bis(pinacolato)diboron. Org. Biomol. Chem., 2023, 21, 5274–5280. (I.F = 3.89).
8. Meena, S.; Dastider, S. G.; Nishad, C. S.; Jangid, D. K.; Kumar, P.; Khirid, S.; Bose, S. K.; Mondal, K.; Banerjee, B.; Dhayal, R. S.; Ag−S Type Quantum Dots versus Superatom Nanocatalyst: A Single Sulfur Atom Modulated Decarboxylative Radical Cascade Reaction. Inorg. Chem. 2023, 62, 6092–6101. (I.F. 5.436).
9. Bhawar, R.; Saini, S.; Nagaraju, D. H.; Bose, S. K.; CeO2-Nanorods Catalyzed Protoboration of Alkenes and Alkynes with Bis(Pinacolato)Diboron. Adv. Synth. Catal. 2023, 365, 584-593 (I.F. 5.981).
10. Prakash, A.; Saini, S.; Basappa, S.; Gupta, D. K.; Mao, L.; Bose, S. K.,* Metal‒Organic Frameworks for Catalytic Construction of C‒B Bond and Related Reactions. ChemCatChem 2022, 15, e202201156. DOI: 10.1002/cctc.202201156 (I.F. 5.501).
11. Saini, S.; Gavali, D. S.; Bhawar, R.; Thapa, R.; Dhayal, R. S.; Bose, S. K.,* Facile synthesis of alkyl- and arylboronate esters enabled by a carbon nanotube supported copper catalyst. Catal. Sci. Technol. 2022, 13, 147-156 (IF. 6.177).
12. Manjunatha, K. K. S.; Nagaraju, D. H.; Yhobu, Z.; Nayan Kumar, H. N.; Budagumpi, S.; Bose, S. K.; Shivakumar, P.; Palakollu, V. N., Tuning the Surface Functionality of Fe3O4 for Sensitive and Selective Detection of Heavy Metal Ions. Sensors 2022, 22, 8895 (IF. 3.847)
13. Shivakumar P,; Manjunatha K. K. S.; Bose, S. K.; Nagaraju D. H., Advances in Zinc and Magnesium Battery Polymer Cathode Materials. ACS Appl. Energy Mater.(IF. 6.024)
14. Basappa, S.; Bhawar, R.; Nagaraju, D. H.; Bose, S. K.,* Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions. Dalton Trans. 2022, 51, 3778–3806 (I.F. 4.569)
15. Bose, S. K. ;* Mao, L.;* Kuehn, L.; Radius, U.;* Nekvinda, J.; Santos, W. L.;* Westcott, S. A.;* Steel, P. G.;* Marder, T. B.,* First-Row d-Block Element-Catalyzed Carbon-Boron Bond Formation and Related Processes. Chem. Rev. 2021, 121, 13238−13341 (I.F. 60.622)
16. Bhawar, R.; Patil, S. K.; Bose, S. K.,* CeO2-nanocubes as efficient and selective catalysts for the hydroboration of carbonyl groups. New J. Chem. 2021, 45, 15028-15034 (I.F. 3.59).
    (Invited article for the special themed issue: Boron & Beyond: Celebrating Todd B. Marder’s Contributions to Chemistry)
17. Shegavi, M. L.; Saini, S.; Bhawar, R.; Vishwantha, M. D.; Bose, S. K.* Recyclable copper nanoparticles‐catalyzed hydroboration of alkenes and β‐borylation of α,β‐unsaturated carbonyl compounds with bis(pinacolato)diboron. Adv. Synth. Catal. 2021, 363, 2408-2416 (I.F. 5.837). (Invited article for the special themed issue: Boron in Catalysis and Organic Synthesis & designated as Very Important Publication)
18. Saini, S.; Agarwal, A.; Bose, S. K.*, Transition Metal Chemistry of Heavier Group 14 Congener Triple-bonded Complexes: Syntheses and Reactivity.Dalton Trans. 2020, 49, 17055-17075
19. Agarwal, A.; Bose, S. K.*, Bonding Relationship between Silicon and Germanium with Group 13 and Heavier Elements of Groups 14–16. Chem. Asian J. 2020, 15, 3784-3806.
    (Invited article for the special themed issue Early Career Researchers)
20. Mao, L.; Bose, S. K.*, Hydroboration of Enynes and Mechanistic Insights. Adv. Synth. Catal. 2020, 362, 4174-4188.
    
21. Shegavi, M. L.; Agarwal, A.; Bose, S. K.,* Efficient synthesis of alkylboronic esters via magnetically recoverable copper nanoparticlecatalyzed borylation of alkyl chlorides and bromides. Green Chem. 2020, 22, 2799–2803.
22. Shegavi, M. L.; Bose, S. K.,* Recent advances in the catalytic hydroboration of carbonyl compounds Catal. Sci. Technol. 2019, 9, 3307–3336.
23. Shegavi, M. L.; Baishya, A.; Geetharani, K.; Bose, S. K.,* Reusable Fe2O3 nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds. Org. Chem. Front. 2018, 5, 3520-3525.
24. Verma, P. K.; Shegavi, M. L.; Bose, S. K.; * Geetharani, K., A nano-catalytic approach for C–B bond formation reactions. Org. Biomol. Chem.2018, 16, 857-873.
25. Scharnagl, F. K.; Bose, S. K.;* Marder, T. B., Acylboranes: synthetic strategies and applications. Org. Biomol. Chem. 2017, 15, 1738-1752. (Selected as Inside Front Cover Page & designated as Hot Article )
26. Bose, S. K.; Brand, S.;OluwatolaOmoregie, H.; Haehnel,M.;Maier, J.; Bringmann, G.;Marder, T. B., Highly efficient synthesis of alkylboronate Esters via Cu(II)-catalyzed borylation of unactivated alkyl bromides and chlorides in air. ACS Catal.2016, 6, 8332.
27. Bose, S. K.; Marder, T. B., A leap ahead for activating C-H bonds, Science2015, 349, 473.
28. Bose, S. K.; Deißenberger, A.; Eichhorn, A.; Steel, P. G.; Lin, Z.; Marder, T. B., Zinc-Catalyzed Dual C-X and C-H Borylation of Aryl Halides. Angew. Chem. Int. Ed.2015, 54, 11843. (Highlighted in: Synfacts 2015, 11(12), 1308; Contributors: P. Knochel, J. M. Hammann)
29. Ji, L.; Fucke, K.; Bose, S. K.; Marder, T. B., Iridium-Catalyzed C-H Borylation of Pyrene: Irreversibility and the Influence of Ligand on Selectivity. J. Org. Chem.2015, 80, 661.
30. Bose, S. K.; Marder, T. B., Efficient Synthesis of Aryl Boronates via Zinc-Catalyzed Cross-Coupling of Alkoxy Diboron Reagents with Aryl Halides at Room Temperature. Org. Lett.2014, 16, 4562. (Highlighted in: Synfacts2014, 10(11), 1193; Contributors: P. Knochel, J. M. Hammann)
31. Bose, S. K.; Fucke, K.; Liu, L.; Steel, P. G.; Marder, T. B., Zinc-Catalyzed Borylation of Primary, Secondary and Tertiary Alkyl Halides with Alkoxy Diboron Reagents at Room Temperature. Angew. Chem. Int. Ed.2014, 53, 1799. (designated as “Hot Paper”). (Highlighted in: Synfacts2014, 10(5), 0516; Contributors: P. Knochel, D. Hass)
32. Roy, D. K.; Bose, S. K.; Anju, R. S.; Mondal, B.; Ramkumar, V.; Ghosh, S., Boron Beyond the Icosahedral Barrier: A 16-Vertex Metallaborane. Angew. Chem. Int. Ed.2013, 52, 3222.
33. Bose, S. K.; Roy, D. K.; Shankhari, P.; Yuvaraj, K.; Mondal, B.; Sikder, A.; Ghosh, S., Syntheses and Characterization of New Vinyl-Borylene Complexes by the Hydroboration of Alkynes with [(m3-BH)(Cp*RuCO)2(m-CO)Fe(CO)3]. Chem.-Eur. J. 2013, 19, 2337.
34. Krishnamoorthy, B. S.; Thakur, A.; Chakrahari, K. K. V.; Bose, S. K.; Hamon, P.; Roisnel, T.; Kahlal, S.; Ghosh, S.; Halet, J-F., Theoretical and Experimental Investigations on Hypoelectronic Heterodimetallaboranes of Group 6 Transition Metals. Inorg. Chem. 2012, 51, 10375.
35. Roy, D. K.; Bose, S. K.; Anju, R. S.; Ramkumar, V.; Ghosh,S., Synthesis and Structure of Dirhodium Analogue of Octaborane-12 and Decaborane-14. Inorg. Chem.2012, 51, 10715.
36. Ponniah, S. J.; Bharathan, J. K.; Bose, S. K.; Ghosh, S., Synthesis and Characterization of Novel Eleven-Vertex Dimetallaheteroborane Clusters Containing Heavier Group 16 Elements. J. Organomet. Chem. 2012, 721-722, 42.
37. Roy, D. K.; Bose, S. K.; Geetharani, K.; Chakrahari, K. K. V.; Mobin, S. M.; Ghosh,S., Synthesis and Structural Characterization of Novel Divanada- and Diniobaboranes Containing Chalcogen Atoms. Chem. Eur. J., 2012, 18, 9983.
38. Ponniah, J.; Bose, S. K.; Ghosh, S., An Eleven-Vertex Metallaborane with TetracappedPentagonal Bipyramidal Geometry. Dalton Trans. 2012, 41, 3627.
39. Geetharani, K.; Bose, S. K.; Ghosh, S., Heterometallic Cubane-Type Clusters Containing Group 13 and 16 Elements. Pure Appl. Chem.2012, 84, 2233.
40. Bose, S. K.; Geetharani, K.; Ghosh, S., C–H activation of arenes and heteroarenes by early transition metallaborane, [(Cp*Ta)2B5H11] (Cp* = η5-C5Me5). Chem. Commun. 2011, 47, 11996.
41. Bose, S. K.; Ghosh, S., Novel 11-vertex, 11-skeletal electron pair tantalaborane of unusual shape.Organometallics2011, 30, 4788.
42. Bose, S. K.; Geetharani, K.; Sahoo, S.; Reddy, K. H. K.; Varghese, B.; Jemmis, E. D.; Ghosh, S., Syntheses, characterization and electronic structures of new type of heterometallic boride clusters. Inorg. Chem.2011, 50, 9414.
43. Bose, S. K.; Ghosh, S., Metallaheteroborane clusters of group 5 transition metals derived from dichalcogenide ligands. J. Organomet. Chem.2011, 696, 3121.
44. Bose, S. K.; Geetharani, K.; Varghese, B.; Ghosh, S., Condensed tantalaborane clusters: synthesis and structures of [(Cp*Ta)2B5H7{Fe(CO)3}2] and [(Cp*Ta)2B5H9{Fe(CO)3}4]. Inorg. Chem.2011, 50, 2445.
45. Geetharani, K.; Bose, S. K.; Sahoo, S.; Varghese, B.; Mobin, S. M.; Ghosh, S., Cluster expansion reactions of group 6 and 8 metallaboranes using transition metal carbonyl compounds of groups 7-9. Inorg. Chem. 2011, 50, 5824.
46. Geetharani, K.; Bose, S. K.; Basak, D.; Suresh, V. M.; Ghosh, S., A new entry into ferraborane chemistry: synthesis and characterization of heteroferraborane complexes. Inorg. Chim. Acta2011, 372, 42.
47. Geetharani, K.; Bose, S. K.; Sahoo, S.; Ghosh, S., A family of heterometallic cubane-type clusters with an exo-Fe(CO)3 fragment anchored to the cubane. Angew. Chem. Int. Ed.2011, 50, 3908.
48. Geetharani, K.; Bose, S. K.; Ghosh, S., Synthesis and structure of [Cp*Ru(CO)2(μ-H){RuFe3(CO)9}]: an unusual mixed-metal tetrahedral cluster with an exopolyhedral metal fragment. Organometallics 2011, 30, 191.
49. Geetharani, K.; Bose, S. K.; Varghese, B.; Ghosh, S., From metallaborane to borylene complexes: syntheses and structures of triply bridged ruthenium and tantalum borylene complexes. Chem. Eur. J. 2010, 16, 11357.
50. Bose, S. K.; Geetharani, K.; Ghosh, S., Ring expansion of a Cp moiety upon CO insertion: synthesis and characterization of [(η6-C6H5OCo)Co3(CO)9]. J. Organomet. Chem.2010, 695, 2567.
51. Bose, S. K.; Geetharani, K.; Varghese, B.; Ghosh, S., Unusual organic chemistry of a metallaborane substrate: formation of a tantalaborane complex with a bridging acyl group (μ-η2). Inorg. Chem.2010, 49, 6375.
52. Bose, S. K.; Geetharani, K.; Ramkumar, V.; Varghese, B.; Ghosh, S., Chemistry of vanadaboranes: synthesis, structures and characterization of organovanadium sulfide clusters with disulfido linkage. Inorg. Chem.2010, 49,2881.
53. Geetharani, K.; Bose, S. K.; Ramkumar, V.; Ghosh, S., An efficient route to group 6 and 8 metallaborane compounds. synthesis of arachno-[Cp*Fe(CO)B3H8] and closo-[(Cp*M)2B5H9] (M = Mo, W). Eur. J. Inorg. Chem.2009, 1483.
54. Bose, S. K.; Geetharani, K.; Ramkumar, V.; Mobin, S. M.; Ghosh, S., Fine-tuning of metallaborane geometries: chemistry of metallaboranes of early transition metals derived from metal halides and monoborane reagents. Chem. Eur. J.2009, 15, 13483.
55. Bose, S. K.; Geetharani, K.; Mobin, S. M.; Ghosh, S., Metallaboranes of the early transition metals: direct synthesis and characterization of (η5-C5Me5Ta)2BnHm (n = 4, m = 10; n = 5, m = 11), (η5-C5Me5Ta)2B5H10(C6H4CH3), and (η5-C5Me5TaCl)2B5H11. Chem. Eur. J.2008, 14, 9058.
56. Bose, S. K.; Ghosh, S.; Noll, B. C.; Halet, J.-F.; Saillard, J.-Y.; Vega, A., Linked and fused tungstaborane clusters: synthesis, characterization, and electronic structures of bis-{(η5-C5Me5W)2B5H8}2 and (η5-C5Me5W)2{Fe(CO)3}nB6-nH10-n, n = 0, 1. Organometallics2007, 26, 5377.

Patent

1. Single-Method for Synthesis of Alkyl 1,2-Bis-Boronate Esters. Inventors: Shubhankar Kumar Bose, Kiran S. Patil, Ramesh Bhawar; Indian Patent; Application No-202341071149 (Published).
2. Transition-Metal and Base-Free Regioselective Synthesis of Alkyl 1,1,2-tris(Boronate esters) from Terminal Alkynes in Water. Inventors: Shubhankar Kumar Bose, Kiran S. Patil, Shivakumar R; Indian Patent; Application No- 202441017524 (Published).