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Publications: Dr. Shubhankar Kumar Bose

List of Publications

  1. Bhawar, R.; Patil, S. K.; Bose, S. K.,* CeO2-nanocubes as efficient and selective catalysts for the hydroboration of carbonyl groups. New J. Chem. 2021, DOI: 10.1039/D1NJ00065A (I.F. 3.28).
    (Invited article for the special themed issue: Boron & Beyond: Celebrating Todd B. Marder’s Contributions to Chemistry)
  2. Shegavi, M. L.; Saini, S.; Bhawar, R.; Vishwantha, M. D.; Bose, S. K.* Recyclable copper nanoparticles‐catalyzed hydroboration of alkenes and β‐borylation of α,β‐unsaturated carbonyl compounds with bis(pinacolato)diboron. Adv. Synth. Catal. 2021, 363, DOI: 10.1002/adsc.202001616. (Invited article for the special themed issue: Boron in Catalysis and Organic Synthesis & designated as Very Important Publication)
  3. Saini, S.; Agarwal, A.; Bose, S. K.*, Transition Metal Chemistry of Heavier Group 14 Congener Triple-bonded Complexes: Syntheses and Reactivity. Dalton Trans. 2020, 49, 17055-17075
  4. Agarwal, A.; Bose, S. K.*, Bonding Relationship between Silicon and Germanium with Group 13 and Heavier Elements of Groups 14–16. Chem. Asian J. 2020, 15, 3784-3806.
    (Invited article for the special themed issue Early Career Researchers)
  5. Mao, L.; Bose, S. K.*, Hydroboration of Enynes and Mechanistic Insights. Adv. Synth. Catal. 2020, 362, 4174-4188.
  6. Shegavi, M. L.; Agarwal, A.; Bose, S. K.,* Efficient synthesis of alkylboronic esters via magnetically recoverable copper nanoparticlecatalyzed borylation of alkyl chlorides and bromides. Green Chem. 2020, 22, 2799–2803.
  7. Shegavi, M. L.; Bose, S. K.,* Recent advances in the catalytic hydroboration of carbonyl compounds Catal. Sci. Technol. 2019, 9, 3307–3336.
  8. Shegavi, M. L.; Baishya, A.; Geetharani, K.; Bose, S. K.,* Reusable Fe2O3 nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds. Org. Chem. Front. 2018, 5, 3520-3525.
  9. Verma, P. K.; Shegavi, M. L.; Bose, S. K.; * Geetharani, K., A nano-catalytic approach for C–B bond formation reactions. Org. Biomol. Chem.2018, 16, 857-873.
  10. Scharnagl, F. K.; Bose, S. K.;* Marder, T. B., Acylboranes: synthetic strategies and applications. Org. Biomol. Chem. 2017, 15, 1738-1752. (Selected as Inside Front Cover Page & designated as Hot Article )
  11. Bose, S. K.; Brand, S.;OluwatolaOmoregie, H.; Haehnel,M.;Maier, J.; Bringmann, G.;Marder, T. B., Highly efficient synthesis of alkylboronate Esters via Cu(II)-catalyzed borylation of unactivated alkyl bromides and chlorides in air. ACS Catal.2016, 6, 8332.
  12. Bose, S. K.; Marder, T. B., A leap ahead for activating C-H bonds, Science2015, 349, 473.
  13. Bose, S. K.; Deißenberger, A.; Eichhorn, A.; Steel, P. G.; Lin, Z.; Marder, T. B., Zinc-Catalyzed Dual C-X and C-H Borylation of Aryl Halides. Angew. Chem. Int. Ed.2015, 54, 11843. (Highlighted in: Synfacts 2015, 11(12), 1308; Contributors: P. Knochel, J. M. Hammann)
  14. Ji, L.; Fucke, K.; Bose, S. K.; Marder, T. B., Iridium-Catalyzed C-H Borylation of Pyrene: Irreversibility and the Influence of Ligand on Selectivity. J. Org. Chem.2015, 80, 661.
  15. Bose, S. K.; Marder, T. B., Efficient Synthesis of Aryl Boronates via Zinc-Catalyzed Cross-Coupling of Alkoxy Diboron Reagents with Aryl Halides at Room Temperature. Org. Lett.2014, 16, 4562. (Highlighted in: Synfacts2014, 10(11), 1193; Contributors: P. Knochel, J. M. Hammann)
  16. Bose, S. K.; Fucke, K.; Liu, L.; Steel, P. G.; Marder, T. B., Zinc-Catalyzed Borylation of Primary, Secondary and Tertiary Alkyl Halides with Alkoxy Diboron Reagents at Room Temperature. Angew. Chem. Int. Ed.2014, 53, 1799. (designated as “Hot Paper”). (Highlighted in: Synfacts2014, 10(5), 0516; Contributors: P. Knochel, D. Hass)
  17. Roy, D. K.; Bose, S. K.; Anju, R. S.; Mondal, B.; Ramkumar, V.; Ghosh, S., Boron Beyond the Icosahedral Barrier: A 16-Vertex Metallaborane. Angew. Chem. Int. Ed.2013, 52, 3222.
  18. Bose, S. K.; Roy, D. K.; Shankhari, P.; Yuvaraj, K.; Mondal, B.; Sikder, A.; Ghosh, S., Syntheses and Characterization of New Vinyl-Borylene Complexes by the Hydroboration of Alkynes with [(m3-BH)(Cp*RuCO)2(m-CO)Fe(CO)3]. Chem.-Eur. J. 2013, 19, 2337.
  19. Krishnamoorthy, B. S.; Thakur, A.; Chakrahari, K. K. V.; Bose, S. K.; Hamon, P.; Roisnel, T.; Kahlal, S.; Ghosh, S.; Halet, J-F., Theoretical and Experimental Investigations on Hypoelectronic Heterodimetallaboranes of Group 6 Transition Metals. Inorg. Chem. 2012, 51, 10375.
  20. Roy, D. K.; Bose, S. K.; Anju, R. S.; Ramkumar, V.; Ghosh,S., Synthesis and Structure of Dirhodium Analogue of Octaborane-12 and Decaborane-14. Inorg. Chem.2012, 51, 10715.
  21. Ponniah, S. J.; Bharathan, J. K.; Bose, S. K.; Ghosh, S., Synthesis and Characterization of Novel Eleven-Vertex Dimetallaheteroborane Clusters Containing Heavier Group 16 Elements. J. Organomet. Chem. 2012, 721-722, 42.
  22. Roy, D. K.; Bose, S. K.; Geetharani, K.; Chakrahari, K. K. V.; Mobin, S. M.; Ghosh,S., Synthesis and Structural Characterization of Novel Divanada- and Diniobaboranes Containing Chalcogen Atoms. Chem. Eur. J., 2012, 18, 9983.
  23. Ponniah, J.; Bose, S. K.; Ghosh, S., An Eleven-Vertex Metallaborane with TetracappedPentagonal Bipyramidal Geometry. Dalton Trans. 2012, 41, 3627.
  24. Geetharani, K.; Bose, S. K.; Ghosh, S., Heterometallic Cubane-Type Clusters Containing Group 13 and 16 Elements. Pure Appl. Chem.2012, 84, 2233.
  25. Bose, S. K.; Geetharani, K.; Ghosh, S., C–H activation of arenes and heteroarenes by early transition metallaborane, [(Cp*Ta)2B5H11] (Cp* = η5-C5Me5). Chem. Commun. 2011, 47, 11996.
  26. Bose, S. K.; Ghosh, S., Novel 11-vertex, 11-skeletal electron pair tantalaborane of unusual shape.Organometallics2011, 30, 4788.
  27. Bose, S. K.; Geetharani, K.; Sahoo, S.; Reddy, K. H. K.; Varghese, B.; Jemmis, E. D.; Ghosh, S., Syntheses, characterization and electronic structures of new type of heterometallic boride clusters. Inorg. Chem.2011, 50, 9414.
  28. Bose, S. K.; Ghosh, S., Metallaheteroborane clusters of group 5 transition metals derived from dichalcogenide ligands. J. Organomet. Chem.2011, 696, 3121.
  29. Bose, S. K.; Geetharani, K.; Varghese, B.; Ghosh, S., Condensed tantalaborane clusters: synthesis and structures of [(Cp*Ta)2B5H7{Fe(CO)3}2] and [(Cp*Ta)2B5H9{Fe(CO)3}4]. Inorg. Chem.2011, 50, 2445.
  30. Geetharani, K.; Bose, S. K.; Sahoo, S.; Varghese, B.; Mobin, S. M.; Ghosh, S., Cluster expansion reactions of group 6 and 8 metallaboranes using transition metal carbonyl compounds of groups 7-9. Inorg. Chem. 2011, 50, 5824.
  31. Geetharani, K.; Bose, S. K.; Basak, D.; Suresh, V. M.; Ghosh, S., A new entry into ferraborane chemistry: synthesis and characterization of heteroferraborane complexes. Inorg. Chim. Acta2011, 372, 42.
  32. Geetharani, K.; Bose, S. K.; Sahoo, S.; Ghosh, S., A family of heterometallic cubane-type clusters with an exo-Fe(CO)3 fragment anchored to the cubane. Angew. Chem. Int. Ed.2011, 50, 3908.
  33. Geetharani, K.; Bose, S. K.; Ghosh, S., Synthesis and structure of [Cp*Ru(CO)2(μ-H){RuFe3(CO)9}]: an unusual mixed-metal tetrahedral cluster with an exopolyhedral metal fragment. Organometallics 2011, 30, 191.
  34. Geetharani, K.; Bose, S. K.; Varghese, B.; Ghosh, S., From metallaborane to borylene complexes: syntheses and structures of triply bridged ruthenium and tantalum borylene complexes. Chem. Eur. J. 2010, 16, 11357.
  35. Bose, S. K.; Geetharani, K.; Ghosh, S., Ring expansion of a Cp moiety upon CO insertion: synthesis and characterization of [(η6-C6H5OCo)Co3(CO)9]. J. Organomet. Chem.2010, 695, 2567.
  36. Bose, S. K.; Geetharani, K.; Varghese, B.; Ghosh, S., Unusual organic chemistry of a metallaborane substrate: formation of a tantalaborane complex with a bridging acyl group (μ-η2). Inorg. Chem.2010, 49, 6375.
  37. Bose, S. K.; Geetharani, K.; Ramkumar, V.; Varghese, B.; Ghosh, S., Chemistry of vanadaboranes: synthesis, structures and characterization of organovanadium sulfide clusters with disulfido linkage. Inorg. Chem.2010, 49,2881.
  38. Geetharani, K.; Bose, S. K.; Ramkumar, V.; Ghosh, S., An efficient route to group 6 and 8 metallaborane compounds. synthesis of arachno-[Cp*Fe(CO)B3H8] and closo-[(Cp*M)2B5H9] (M = Mo, W). Eur. J. Inorg. Chem.2009, 1483.
  39. Bose, S. K.; Geetharani, K.; Ramkumar, V.; Mobin, S. M.; Ghosh, S., Fine-tuning of metallaborane geometries: chemistry of metallaboranes of early transition metals derived from metal halides and monoborane reagents. Chem. Eur. J.2009, 15, 13483.
  40. Bose, S. K.; Geetharani, K.; Mobin, S. M.; Ghosh, S., Metallaboranes of the early transition metals: direct synthesis and characterization of (η5-C5Me5Ta)2BnHm (n = 4, m = 10; n = 5, m = 11), (η5-C5Me5Ta)2B5H10(C6H4CH3), and (η5-C5Me5TaCl)2B5H11. Chem. Eur. J.2008, 14, 9058.
  41. Bose, S. K.; Ghosh, S.; Noll, B. C.; Halet, J.-F.; Saillard, J.-Y.; Vega, A., Linked and fused tungstaborane clusters: synthesis, characterization, and electronic structures of bis-{(η5-C5Me5W)2B5H8}2 and (η5-C5Me5W)2{Fe(CO)3}nB6-nH10-n, n = 0, 1. Organometallics2007, 26, 5377.

 
 

 
       
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